Just to let you know that characteristics also make a differance to EVs.
Also a question. Say I got a pkmn I wanted to EV train at Lv1 and had a lot of rare candy's (that I got through uh *cough* a um.. a friend ) Would I be able to use these rare candies on my Lv1 pokemon to get it to level 60ish and then still have 0EVs?
Yes. You can also use the Pokemon Daycare to do so.