I think I figured out what I was doing wrong.
And about the IVs changing from frames. I must have read someone's post wrong and assumed they meant PID frames when they were talking about IV frames. Ignore that part.
Attempting my catch again this morning! There is a moving NPC in the area so it is a pain with the fluctuating Timer0.
Also, thanks for the help!
Edit: Well after 6 or so hours of trying to get my Magnemite... I keep hitting the 2 frames around him. I chatter 67 times for ever and hit the stupid Koffing before him multiple times. Start chatting 68 times and then hit the male Koffing after him! :|
Edit2: This entire time I was in Virbank Complex trying to get a Magnemite. I got frustrated after many hours. I make a trip to P2 Labs just to see if a Magneton would be easier due to less people around? 2nd try I get it... So, if anyone is attempting to RNG for a Magne(ton,zone,mite), I would suggest going to P2 instead. :|