Ash's Kingler, Tauros, and Muk
Ash's Torkoal and Torterra
Ash's Gible and Dawn's Togekiss
Misty's Starmie and Horsea
Brock's Geodude and Onix
How can anyone not believe Alder's Volcarona is his best Pokemon? That thing is tough to take out even with physical water type, unless you are like, 20 lvls higher than it, and even then sometimes it wont OHKO it.
Only Rock Slide and Stone Edge will OHKO that thing and even then you gotta be at least 10 lvls higher than it.
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Battle wise totodile and torterra, appearance wise, kingler and muk
Ash's Glalie, I mean, seriously. Being captured a few episodes before the League, having one mini plot, and then being ditched never to be seen again? (ok, it got a cameo in DP but still).
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I say Pidgeot. Main reason is coz Ash said that he will come back for it and it's 14/15 seasons later and Ash still hasn't gone back. What the heck writers?!
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Paplitoad right now seriously has the worse treatment of all the Unova Pokemon and likely his entire team. He started with great personality that could have been carried throughout battle but they nerfed it greatly unlike the other water types had. He was supposed to be Ash's water Pokemon battler when Oshawott was not but he has been absent throughout majority of Unova and outside of gyms and tournaments. He cannot beat Oshawott in entertainment and he does not appear at all. WORSE PART is he has no role on Ash's team anymore. Everybody had done something outside of battling but the Toad. The reason he is really on the team is for evolution and if he does not evolve, his capture will be meaningless. It is very sad.
Yeah..... I changed my signature....
Kingler, Muk and Tauros by a long shot.
MEowth should have gotten more battles, because he talks hes just the IDEA GUY for team rocket
meowth got no battles (with the exection of the contest for the togepi and randomly using a desperate frurry swipes nowadays.. just because he talks he's more of a trainer than a pokemon and I would not be surprised if he became one
Pikachu can't really be said because if it was super over poweted from the beginning of each region, it would just destroy every pokemon until the league.